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Shiqu CHEN, Silei XIANG, Zehao TAN, Huiyuan LI, Xiaohui YAN, Jiewei YIN, Shuiyun SHEN, Junliang ZHANG
《能源前沿(英文)》 2023年 第17卷 第1期 页码 123-133 doi: 10.1007/s11708-022-0849-1
关键词: proton exchange membrane fuel cells (PEMFCs) non-precious metal catalyst (NPMC) cathode catalyst layer (CCL) local and bulk oxygen transport resistance
用于储能设备的一种新型高导电性和高选择性质子交换膜 Article
Kang Huang, Shuhao Lin, Yu Xia, Yongsheng Xia, Feiyan Mu, Yuqin Lu, Hongyan Cao, Yixing Wang, Weihong Xing, Zhi Xu
《工程(英文)》 2023年 第28卷 第9期 页码 69-78 doi: 10.1016/j.eng.2022.11.008
Ion conductive membranes (ICMs) with highly conductive proton selectivity are of significant importance and greatly desired for energy storage devices. However, it is extremely challenging to construct fast proton-selective transport channels in ICMs. Herein, a membrane with highly conductive proton selectivity was fabricated by incorporating porous carbon sieving nanospheres with a hollow structure (HCSNs) in a polymer matrix. Due to the precise ion sieving ability of the microporous carbon shells and the fast proton transport through their accessible internal cavities, this advanced membrane presented a proton conductivity (0.084 S·cm−1) superior to those of a commercial Nafion 212 (N212) membrane (0.033 S·cm−1) and a pure polymer membrane (0.049 S·cm−1). The corresponding proton selectivity of the membrane (6.68 × 105 S·min·cm−3) was found to be enhanced by about 5.9-fold and 4.3-fold, respectively, compared with those of the N212 membrane (1.13 × 105 S·min·cm−3) and the pure membrane (1.56 × 105 S·min·cm−3). Low-field nuclear magnetic resonance (LF-NMR) clearly revealed the fast proton-selective transport channels enabled by the HCSNs in the polymeric membrane. The proposed membrane exhibited an outstanding energy efficiency (EE) of 84% and long-term stability over 1400 cycles with a 0.065% capacity decay per cycle at 120 mA·cm−2 in a typical vanadium flow battery (VFB) system.
关键词: Ion conductive membrane Hollow carbon sieving nanosphere Proton transport channel Flow battery
唐勇,孙小菡,张明德,丁东
《中国工程科学》 2001年 第3卷 第12期 页码 71-75
提出了一种带有光监控通道(OSC)子系统的光传送网(OTN)分层结构模型,分析了OSC中的信号特点,指出OSC信号质量决定了运行、管理和维护(OAM)信号的可靠性。依据Q值与误码率(BER)的一一对应关系,提出了一种可在线监测OSC信号Q值的方案,并基于数字信号处理芯片(DSP)技术设计了监测模块,实现了OSC信号在线Q值监测。
TiO supported IrO for anode reversal tolerance in proton exchange membrane fuel cell
《能源前沿(英文)》 2022年 第16卷 第5期 页码 852-861 doi: 10.1007/s11708-021-0811-7
关键词: proton exchange membrane fuel cell (PEMFC) fuel starvation cell reverse reversal tolerance anode oxygen evolution reaction
Fabrication and performance of PEN SOFCs with proton-conducting electrolyte
ZHONG Li, LUO Jingli, Karl Chuang
《化学科学与工程前沿(英文)》 2007年 第1卷 第1期 页码 40-44 doi: 10.1007/s11705-007-0008-6
关键词: proton-conducting positive-electrolyte-negative temperature operation Mo-Ni-S-based composite advantageous
《化学科学与工程前沿(英文)》 2022年 第16卷 第12期 页码 1772-1781 doi: 10.1007/s11705-022-2197-4
关键词: CO2 electrolysis single-atom catalysts spin polarization proton dynamics in situ IR spectroscopy kinetic isotope effect
齐璞,孙赞盈,齐宏海
《中国工程科学》 2014年 第16卷 第8期 页码 64-68
黄河下游的堤防是按照小浪底建库前千年洪水设防水位,加超高2.5 m或3 m设计,堤后淤背宽度百米,小浪底水库投入运用后下游宽河道段河槽下切2 米多,下游窄河段下切1 米多;在洪水不断减小的新形势下,防洪形势发生根本性变化,今后不存在大堤决口的可能。其合理的治理目标是,在中游完善以小浪底水库为中心的调水调沙体系,使更多泥沙由洪水输送;在下游进行双向河槽整治,稳定河槽,形成高效排洪输沙通道;控制河床不发生过渡冲刷,保证两岸引水,使洪水不漫滩;彻底解放黄河下游滩区和防洪中横河斜河等诸多问题,使黄河彻底由害河变为利河。
design of novel proton-pump inhibitors with reduced adverse effects
Xiaoyi Li, Hong Kang, Wensheng Liu, Sarita Singhal, Na Jiao, Yong Wang, Lixin Zhu, Ruixin Zhu
《医学前沿(英文)》 2019年 第13卷 第2期 页码 277-284 doi: 10.1007/s11684-018-0630-3
关键词: proton-pump inhibitor adverse effect pharmacological mechanism toxicological mechanism pKa calculation
The source and transport of bioaerosols in the air: A review
《环境科学与工程前沿(英文)》 2021年 第15卷 第3期 doi: 10.1007/s11783-020-1336-8
• Emission of microbe from local environments is a main source of bioaerosols.
关键词: Bioaerosols Diffusion Source identification Biogeography
A cellphone-based colorimetric multi-channel sensor for water environmental monitoring
《环境科学与工程前沿(英文)》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1590-z
● A cellphone-based colorimetric multi-channel sensor for in-field detection.
关键词: Colorimetric analysis Multi-channel sensor Cellphone Water quality indexes Environmental monitoring
Analysis of nonlinear channel friction inverse problem
CHENG Weiping, LIU Guohua
《结构与土木工程前沿(英文)》 2007年 第1卷 第2期 页码 205-210 doi: 10.1007/s11709-007-0024-0
Ionic liquid modified Pt/C electrocatalysts for cathode application in proton exchange membrane fuel
Huixin Zhang, Jinying Liang, Bangwang Xia, Yang Li, Shangfeng Du
《化学科学与工程前沿(英文)》 2019年 第13卷 第4期 页码 695-701 doi: 10.1007/s11705-019-1838-8
关键词: ionic liquid PEMFC electrode oxygen reduction reaction electrocatalyst adsorption
Ruiqing Wang, Xiaolan Cao, Sheng Sui, Bing Li, Qingfeng Li
《化学科学与工程前沿(英文)》 2022年 第16卷 第3期 页码 364-375 doi: 10.1007/s11705-021-2052-z
关键词: Pt nanowires morphology structure control in situ growth mechanism proton exchange membrane fuel cells
Intercontinental transport of air pollution
Lin ZHANG,
《环境科学与工程前沿(英文)》 2010年 第4卷 第1期 页码 20-29 doi: 10.1007/s11783-010-0014-7
标题 作者 时间 类型 操作
Exploration of the oxygen transport behavior in non-precious metal catalyst-based cathode catalyst layerfor proton exchange membrane fuel cells
Shiqu CHEN, Silei XIANG, Zehao TAN, Huiyuan LI, Xiaohui YAN, Jiewei YIN, Shuiyun SHEN, Junliang ZHANG
期刊论文
用于储能设备的一种新型高导电性和高选择性质子交换膜
Kang Huang, Shuhao Lin, Yu Xia, Yongsheng Xia, Feiyan Mu, Yuqin Lu, Hongyan Cao, Yixing Wang, Weihong Xing, Zhi Xu
期刊论文
Fabrication and performance of PEN SOFCs with proton-conducting electrolyte
ZHONG Li, LUO Jingli, Karl Chuang
期刊论文
Spin polarization strategy to deploy proton resource over atomic-level metal sites for highly selective
期刊论文
design of novel proton-pump inhibitors with reduced adverse effects
Xiaoyi Li, Hong Kang, Wensheng Liu, Sarita Singhal, Na Jiao, Yong Wang, Lixin Zhu, Ruixin Zhu
期刊论文
Ionic liquid modified Pt/C electrocatalysts for cathode application in proton exchange membrane fuel
Huixin Zhang, Jinying Liang, Bangwang Xia, Yang Li, Shangfeng Du
期刊论文
Study on the growth of platinum nanowires as cathode catalysts in proton exchange membrane fuel cells
Ruiqing Wang, Xiaolan Cao, Sheng Sui, Bing Li, Qingfeng Li
期刊论文